You have no record in your Windows DNS server for the "Diskstation" host.
#Synology wins server setup Pc#
Your PC is using the Windows server as its DNS server.Anyone using the router as their DNS server will have those host names resolved.
Your router is aware of the host names of the devices that requested DHCP from it, and it adds those host names to its internal name (DNS) records. Your DHCP is being handed out by your router, and in those DHCP settings it's giving out itself as the DNS server for clients to use. Your "Diskstation" NAS is using DHCP to get it's IP. Ok, based on what you've said here's my guess/suggestions.
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